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⟩ Explain me how pipe flanges are electrically insulated?

Pipe flanges are protected from corrosion by means of electrolysis, with dielectric flanges. The piping system is electrically insulated by what is called a sacrificial anode. A bag of readily corrodible metal is buried in the ground with a wire running from the pipe to the bag so that the sacrificial anode will corrode first. If any electrical current charges the pipe, it also serves as a ground.

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