121⟩ What does Thermodynamics helps in predicting?
Predicting the feasibility of reaction and does not indicate the rate of chemical reaction
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Predicting the feasibility of reaction and does not indicate the rate of chemical reaction
Phenolphthalein, PH range 8.3 to 10.0
Henderson’s equation
Rates and mechanisms of chemical and Biochemical reactions
Sulphur
S8 molecule (octa atomic)
Rate of reaction can be expressed as –dc/dt where dc is small decreasing concentration in time dt seconds, (-) sign indicates that the concentration decreases with time.
Doubled
The difference of Enthalpy’s of products and reactants H=Hp-Hr
The amount of heat liberated of absorbed when one mole of compound is formed in its standard state from its elements in their standard state is called standard heat of formation ( Hf *)
Every substance poses definite amount of energy called internal energy or intrinsic energy (E).
The amount of heat liberated when one mole of any substance is completely burnt in oxygen is called heat of combustion H is negative for heat of combustion.
1st law of thermodynamics may be represented as q= E-W
According to this law the energy can neither be created nor destroyed, but can be converted into one form to another.
Kc is the equilibrium constants when the concentrations are expressed in moles/litre
Kc = product of concentrate ions of products / product of concentrate ions of reactants
A Galvanic cell or voltaic cell or electrochemical cell is a system in which a spontaneous chemical oxidation- reduction occurs and generates electrical energy.
Standard hydrogen electrode was taken as reference electrode whose potential is assumed zero.
E = Eo + (2.303RT /nF) log [Oxidation form]/[reduced form]
The strength of the Electrolyte
Reason for flow of current is that moment of free electrons from higher negative potential to a lower positive potential region.
Electrochemistry